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LSD has two labile protons on the tertiary stereogenic C5 and C8 positions, rendering these centers liable to epimerisation. The C8 proton is much more labile as a result of electron-withdrawing carboxamide attachment, but removing of the chiral proton in the C5 position (which was once also an alpha proton of the mum or dad molecule tryptophan) is assisted via the inductively withdrawing nitrogen and pi electron delocalisation Using the indole ring.[citation needed]
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ALD-fifty two is homologous to 1P-LSD, which contains a propionyl group bound to CH3CO- instead of the acetyl group certain to the same site. It is actually mysterious how these variances account for differences in The 2 compound’s action.
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